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Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement
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https://doi.org/10.3762/bjoc.15.160Abstract
An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally simple.
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