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A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations.
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https://doi.org/10.1039/c5cc04677gAbstract
Here we report the use of 10-phenylphenothiazine (PTH) as an inexpensive, highly reducing metal-free photocatalyst for the reduction of carbon-halogen bonds via the trapping of carbon-centered radical intermediates with a mild hydrogen atom donor. Dehalogenations were carried out on various substrates with excellent yields at room temperature in the presence of air.
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