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Open Access Publications from the University of California

Supramolecular control of reverse spin transitions in cobalt(II) terpyridine complexes with diblock copolypeptide amphiphiles

  • Author(s): Kuroiwa, K
  • Arie, T
  • Sakurai, S
  • Hayami, S
  • Deming, TJ
  • et al.

© The Royal Society of Chemistry 2015. Three composites composed of the cobalt terpyridine complex [CoII(MeO-terpy)2] and the diblock copolypeptide amphiphiles 1 and 2 or the polypeptide 3 (including glutamic acid and leucine) were prepared. Supramolecular structures such as rectangular morphologies were obtained from composites of 1 and 2. A perfectly reversible reverse spin transition was successfully generated in the case of composites made with 1.

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