Supramolecular control of reverse spin transitions in cobalt(II) terpyridine complexes with diblock copolypeptide amphiphiles
- Author(s): Kuroiwa, K
- Arie, T
- Sakurai, S
- Hayami, S
- Deming, TJ
- et al.
Published Web Locationhttps://doi.org/10.1039/c5tc00677e
© The Royal Society of Chemistry 2015. Three composites composed of the cobalt terpyridine complex [CoII(MeO-terpy)2] and the diblock copolypeptide amphiphiles 1 and 2 or the polypeptide 3 (including glutamic acid and leucine) were prepared. Supramolecular structures such as rectangular morphologies were obtained from composites of 1 and 2. A perfectly reversible reverse spin transition was successfully generated in the case of composites made with 1.
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