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Copper‐Catalyzed Regioselective ortho CH Cyanation of Vinylarenes
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https://doi.org/10.1002/anie.201402449Abstract
A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives. A copper-catalyzed cyanative dearomatization mechanism is proposed to account for the regiochemical course of this reaction.
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