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The Isolation of a Large Cyclopentadienylcobaltsulfide Cluster. The Synthesis and Crystal Structure of Octahedral closo-(η5-C5H5Co)5S

  • Author(s): Holland, Ryan L.
  • O’Connor, Joseph M.
  • Rheingold, Arnold L.
  • et al.
Abstract

The title cluster, which was obtained serendipitously when (η5-C5H5)Co(PPh3)2 was added to a (η5-C5H5)Co metallacyclobutene containing a sulfone group, is the largest cluster known, formed primarily with (η5-C5H5)Co vertices. The closo-(η5-C5H5Co)5S is a closed-shell, octahedral cluster which forms black, monoclinic crystals from methanol.

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