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Synthesis and structural studies of bridgehead dienes 3 - oxobicyclo[6.3.1]dodeca -1(11),8(9) - diene - (zz) -11- carboxylic acid and 3 - oxobicyclo[7.3.1]trideca -1(12),9(10) - diene - (zz) - 12 - carboxylic acid
Abstract
Single crystal X-ray structures of two bridgehead dienes are reported. The bridgehead double bonds of diene 7 show only modest deviation from strain-free tetrasubstituted double bonds. The double bonds in bridgehead diene 6, however, exhibit an average deviation of the C-CC-C torsion angle (φ + χ) of 14°. © 1986.
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