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Gold( i )-catalyzed enantioselective bromocyclization reactions of allenes
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https://doi.org/10.1039/c3sc50811kAbstract
The enantioselective bromocyclization of allenes is accomplished through the use of a chiral dinuclear gold complex and/or chiral phosphate anions in the presence of an N-bromolactam as an electrophilic bromine source. This method provides access to heterocyclic vinyl bromides with an allylic stereocenter in excellent yield and enantioselectivity. These enantioenriched vinyl bromides may serve as a handle for further derivatization via cross-coupling reactions. © 2013 The Royal Society of Chemistry.
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