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Atropurpuran—missing biosynthetic link leading to the hetidine and arcutine C20-diterpenoid alkaloids or an oxidative degradation product?
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https://doi.org/10.1016/j.tetlet.2015.01.111Abstract
A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.
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