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C–H Insertion Reactions of Donor/Donor Carbenes: Inception, Investigation, and Insights

Published Web Location

https://doi.org/10.1055/s-0039-1691738
Abstract

Insertion reactions of donor/donor carbenes have emerged from obscurity to become a versatile method for the synthesis of a variety of cyclic structures with excellent control of diastereo- and enantioselectivity. This Account describes the origin of this project as part of a natural product synthesis and the ensuing decade of reaction development that has resulted in new asymmetric methods as well as intriguing tangential observations.

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