Department of Earth System Science

Trichlorofluoromethane (CCl₃F; CFC-11) and dichlorodifluoromethane (CCl₂F₂; CFC-12) have been widely used as tracers of oceanic circulation and mixing on decadal timescales. In order to estimate their transfer rate across the air-sea interface, liquid-phase diffusion coefficients are needed In this study the diffusivities of CFC-11 and CFC-12 in pure water were measured over the temperature range 0.6–30°C. Diffusivities of CFC-11 in pure water ranged from (5.24±0.25)×10⁻⁶ cm²S⁻¹ at 0.6°C to (1.13±0.05)×10⁻⁵ cm²S⁻¹ at 30.3°C and a fit to the data yielded the equation D _CFC-11 = 0.015 exp (−18.1/RT), where R is the universal gas constant in kJ mol⁻¹ K⁻¹ and T is the temperature in Kelvin. Diffusivities of CFC-12 in pure water ranged from (5.38±0.22)×10⁻⁶ cm² s⁻¹ at 0.6°C to (1.26±0.05)×10⁻⁵ cm² s⁻¹at 30.3°C and the temperature dependence can be expressed as D_CFC-12= 0.036 exp (−20.1/RT). The estimated uncertainty in both equations is <3%. Experiments were also carried out in seawater for each compound. For CFC-11 the diffusivity in seawater was not significantly different from that in pure water. However, the diffusivity of CFC-12 in seawater was found to be 7.2±3.0% lower than that in pure water. Schmidt numbers for both CFC-11 and CFC-12 in pure water and seawater were estimated from the data.