Lawrence Berkeley National Laboratory
Radiation enhanced diffusion of cesium, strontium, and europium in silicon carbide
- Author(s): Dwaraknath, SS
- Was, GS
- et al.
Published Web Locationhttps://doi.org/10.1016/j.jnucmat.2016.02.034
The radiation enhanced diffusion (RED) of three key fission products in SiC: cesium, europium, and strontium was investigated following ion irradiation at a damage rate of 4.6 × 10-4dpa s-1at temperatures between 900° C and 1100° C. The radiation enhancement of diffusion was as large as 107at 900° C, and dropped to a value of 1 by 1300° C for all but cesium grain boundary diffusion. Strontium and cesium exhibited several orders of magnitude enhancement for both mechanisms. Europium enhancement was greatest at 900° C, but dropped to the thermal rates at 1100° C for both mechanisms. The trends in the RED mechanism correlated well with the point defect concentrations suggesting that both carbon and silicon vacancy concentrations are important for fission product diffusion. These constitute the first radiation-enhanced diffusion measurements of strontium, cesium and europium in SiC.