Skip to main content
Open Access Publications from the University of California

Novel weak coordination to silylium ions: Formation of nearly linear Si-H-Si bonds

  • Author(s): Hoffmann, SP
  • Kato, T
  • Tham, FS
  • Reed, CA
  • et al.

Published Web Location

The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si-H-SiR3+cations. © The Royal Society of Chemistry 2006.

Many UC-authored scholarly publications are freely available on this site because of the UC Academic Senate's Open Access Policy. Let us know how this access is important for you.

Main Content
Current View