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Novel weak coordination to silylium ions: Formation of nearly linear Si-H-Si bonds

  • Author(s): Hoffmann, SP
  • Kato, T
  • Tham, FS
  • Reed, CA
  • et al.

Published Web Location

https://doi.org/10.1039/b511344j
Abstract

The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si-H-SiR3+cations. © The Royal Society of Chemistry 2006.

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