Lawrence Berkeley National Laboratory

The quasi Fermi level splitting is measured for Cu(In,Ga)Se2 absorber layers with different copper to (indium + gallium) ratios and for different gallium contents in the range of 20%-40%. For absorbers with a [Cu]/[In + Ga] ratio below one, the measured quasi Fermi level splitting is 120 meV higher compared to absorbers grown under copper excess independent of the gallium content, contrary to the ternary CuInSe2 where the splitting is slightly higher for absorber layers grown under copper excess. Possible explanations are the gallium gradient determined by the secondary ion mass spectrometry measurement which is less pronounced towards the surface for stoichiometric absorber layers or a fundamentally different recombination mechanism in the presence of gallium. Comparing the quasi Fermi level splitting of an absorber to the open circuit voltage of the corresponding solar cell, the difference for copper poor cells is much lower (60 meV) than that for copper rich cells (140 meV). The higher loss in V OC in the case of the Cu-rich material is attributed to tunneling enhanced recombination due to higher band bending within the space charge region.