Lawrence Berkeley National Laboratory
Homoleptic U(iii) and U(iv) amidate complexes.
- Author(s): Straub, MD
- Hohloch, S
- Minasian, SG
- Arnold, J
- et al.
Published Web Locationhttps://doi.org/10.1039/c7dt04813k
The syntheses of the first homoleptic U(iii) and U(iv) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(iii) complex to eight in the U(iv) complex in the solid state structures.