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Open Access Publications from the University of California

Homoleptic U(iii) and U(iv) amidate complexes.

  • Author(s): Straub, MD
  • Hohloch, S
  • Minasian, SG
  • Arnold, J
  • et al.

The syntheses of the first homoleptic U(iii) and U(iv) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(iii) complex to eight in the U(iv) complex in the solid state structures.

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