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Homoleptic U( iii ) and U( iv ) amidate complexes
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https://doi.org/10.1039/c7dt04813kAbstract
The syntheses of the first homoleptic U(iii) and U(iv) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(iii) complex to eight in the U(iv) complex in the solid state structures.
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