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Selective Propene Oligomerization with Nickel(II)-Based Metal–Organic Frameworks
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https://doi.org/10.1021/cs401189aAbstract
Two Ni2+-containing metal-organic frameworks, Ni 2(dobdc) and Ni2(dobpdc), are shown to be active for the oligomerization of propene in the gas phase. The metal-organic frameworks exhibit activity comparable to Ni2+-exchanged aluminosilicates but maintain high selectivity for linear oligomers. Thus, these frameworks should enable the high yielding synthesis of linear propene oligomers for use in detergent and diesel fuel applications. © 2014 American Chemical Society.
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