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Et(2)Al(+) alumenium ion-like chemistry. synthesis and reactivity toward alkenes and alkene oxides.

  • Author(s): Kim, Kee-Chan;
  • Reed, Christopher A;
  • Long, Gregory S;
  • Sen, Ayusman
  • et al.

Published Web Location

https://doi.org/10.1021/ja0259990
Abstract

Inert weakly coordinating carborane anions, CB(11)H(6)X(6)(-) (X = Cl, Br), allow access to the long sought, highly electrophilic diethylaluminum moiety in Et(2)Al(CB(11)H(6)X(6)). X-ray crystallography reveals ion-like structural features reminiscent of the corresponding trialkylsilylium species. Et(2)Al(CB(11)H(6)X(6)) is a potent catalyst for the electrophilic ethenation of benzene, the polymerization of cyclohexene oxide, and the oligomerization of ethene to a low molecular weight, highly branched product.

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