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Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers
- Author(s): Su, Gregory M;
- Wang, Han;
- Barnett, Brandon R;
- Long, Jeffrey R;
- Prendergast, David;
- Drisdell, Walter S
- et al.
Published Web Locationhttps://doi.org/10.1039/d0sc06038k
In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.
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