Kinetically E-selective macrocyclic ring-closing metathesis

2017

et al.

Published Web Location

https://doi.org/10.1038/nature20800

Abstract

Ring-closing metathesis is a widely used chemical transformation that can generate organic macrocycle compounds; here, an approach is described by which the E-stereoisomer of a macrocycle is generated selectively, exemplified by synthesizing the antibiotic recifeolide and the anti-cancer drug pacritinib.

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UC Riverside

Kinetically E-selective macrocyclic ring-closing metathesis

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