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Panchromatic photoproduction of H2with surface plasmons

  • Author(s): Mubeen, S
  • Lee, J
  • Liu, D
  • Stucky, GD
  • Moskovits, M
  • et al.

Published Web Location

http://pubs.acs.org/articlesonrequest/AOR-ZM6pfjwwIVUiSZdrKTyX
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Public License
Abstract

© 2015 American Chemical Society. The optical resonances of plasmonic nanostructures depend critically on the geometrical details of the absorber. We show that this unique property of plasmons can potentially be used to create panchromatic absorbers covering most of the useful solar spectrum, by measuring the light-to-hydrogen conversion capabilities of a series multielectrode photocatalytic devices, based on functionalized gold nanorods of appropriately chosen aspect ratios. Judiciously combining nanorods of various aspect ratios almost doubles the H2production of the device over what is optimally possible with a device using gold nanorods of a single aspect ratio (all other key parameters being equal). The estimated quantum efficiency (absorbed photons-to-hydrogen) averaged over the entire solar spectrum of the best performing plasmonic multielectrode array was approximately 0.1%, and the measured H2production rate for all of the devices was found to be approximately proportional to the hot electron generation. The device was monitored continuously for over 200 hr of operation without measurable diminution in the rate.

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