The nature and role of bridged carbonyl intermediates in the ultrafast photo-induced rearrangement of Ru3(CO)12.
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The nature and role of bridged carbonyl intermediates in the ultrafast photo-induced rearrangement of Ru3(CO)12.

  • Author(s): Glascoe, Elizabeth A.
  • Kling, Matthias F.
  • Shanoski, Jennifer E.
  • Harris, Charles B.
  • et al.
Abstract

The photochemistry of the trimetal cluster,Ru(3)(CO)12, was investigated on the ultrafast timescale using UV-vis pump, infrared probe spectroscopy in order to study the transient intermediates formed upon photoexcitation.

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