Lithium superionic conductors (LSCs) are of major importance as solid
electrolytes for next-generation all-solid-state lithium-ion batteries. While
$ab$ $initio$ molecular dynamics have been extensively applied to study these
materials, there are often large discrepancies between predicted and
experimentally measured ionic conductivities and activation energies due to the
high temperatures and short time scales of such simulations. Here, we present a
strategy to bridge this gap using moment tensor potentials (MTPs). We show that
MTPs trained on energies and forces computed using the van der Waals optB88
functional yield much more accurate lattice parameters, which in turn leads to
accurate prediction of ionic conductivities and activation energies for the
Li$_{0.33}$La$_{0.56}$TiO$_3$, Li$_3$YCl$_6$ and Li$_7$P$_3$S$_{11}$ LSCs. NPT
MD simulations using the optB88 MTPs also reveal that all three LSCs undergo a
transition between two quasi-linear Arrhenius regimes at relatively low
temperatures. This transition can be traced to an expansion in the number and
diversity of diffusion pathways, in some cases with a change in the
dimensionality of diffusion. This work presents not only an approach to develop
high accuracy MTPs, but also outlines the diffusion characteristics for LSCs
which is otherwise inaccessible through $ab$ $initio$ computation.