- Liu, Huang;
- Liu, Bei;
- Lin, Li-Chiang;
- Chen, Guangjin;
- Wu, Yuqing;
- Wang, Jin;
- Gao, Xueteng;
- Lv, Yining;
- Pan, Yong;
- Zhang, Xiaoxin;
- Zhang, Xianren;
- Yang, Lanying;
- Sun, Changyu;
- Smit, Berend;
- Wang, Wenchuan
Removal of carbon dioxide is an essential step in many energy-related processes. Here we report a novel slurry concept that combines specific advantages of metal-organic frameworks, ion liquids, amines and membranes by suspending zeolitic imidazolate framework-8 in glycol-2-methylimidazole solution. We show that this approach may give a more efficient technology to capture carbon dioxide compared to conventional technologies. The carbon dioxide sorption capacity of our slurry reaches 1.25 mol l(-1) at 1 bar and the selectivity of carbon dioxide/hydrogen, carbon dioxide/nitrogen and carbon dioxide/methane achieves 951, 394 and 144, respectively. We demonstrate that the slurry can efficiently remove carbon dioxide from gas mixtures at normal pressure/temperature through breakthrough experiments. Most importantly, the sorption enthalpy is only -29 kJ mol(-1), indicating that significantly less energy is required for sorbent regeneration. In addition, from a technological point of view, unlike solid adsorbents slurries can flow and be pumped. This allows us to use a continuous separation process with heat integration.