Photons do not carry sufficient momentum to induce indirect optical
transitions in semiconducting materials such as silicon, necessitating the
assistance of lattice phonons to conserve momentum. Compared to direct bandgap
semiconductors, this renders silicon a less attractive material for a wide
variety of optoelectronic applications. In this work, we introduce an
alternative strategy to fulfill the momentum-matching requirement in indirect
optical transitions. We demonstrate that when confined to scales below ~3 nm,
photons acquire sufficient momentum to allow electronic transitions at the band
edge of Si without the assistance of a phonon. Confined photons allow
simultaneous energy and momentum conservation in two-body photon-electron
scattering; in effect, converting silicon into a direct bandgap semiconductor.
We show that this less explored concept of light-matter interaction leads to a
marked increase of the absorptivity of Si from the UV to the near-IR. The
strategy provides opportunities for more efficient use of indirect
semiconductors in photovoltaics, energy conversion, light detection and
emission.