Analog quantum simulation is expected to be a significant application of near-term quantum devices. Verification of these devices without comparison to known simulation results will be an important task as the system size grows beyond the regime that can be simulated classically. We introduce a set of experimentally-motivated verification protocols for analog quantum simulators, discussing their sensitivity to a variety of error sources and their scalability to larger system sizes. We demonstrate these protocols experimentally using a two-qubit trapped-ion analog quantum simulator and numerically using models of up to five qubits.

Realistic quantum sensors face a trade-off between the number of sensors measured in parallel and the control and readout fidelity (F) across the ensemble. We investigate how the number of sensors and fidelity affect sensitivity to continuous and intermittent signals. For continuous signals, we find that increasing the number of sensors by 1/F2 for F<1 always recovers the sensitivity achieved when F=1. However, when the signal is intermittent, more sensors are needed to recover the sensitivity achievable with one perfect quantum sensor. We also demonstrate the importance of near-unity control fidelity and readout at the quantum projection noise limit by estimating the frequency components of a stochastic, intermittent signal with a single trapped ion sensor. Quantum sensing has historically focused on large ensembles of sensors operated far from the standard quantum limit. The results presented in this paper show that this is insufficient for quantum sensing of intermittent signals and reemphasizes the importance of the unique scaling of quantum projection noise near an eigenstate.

Many important chemical and biochemical processes in the condensed phase are notoriously difficult to simulate numerically. Often, this difficulty arises from the complexity of simulating dynamics resulting from coupling to structured, mesoscopic baths, for which no separation of time scales exists and statistical treatments fail. A prime example of such a process is vibrationally assisted charge or energy transfer. A quantum simulator, capable of implementing a realistic model of the system of interest, could provide insight into these processes in regimes where numerical treatments fail. We take a first step towards modeling such transfer processes using an ion-trap quantum simulator. By implementing a minimal model, we observe vibrationally assisted energy transport between the electronic states of a donor and an acceptor ion augmented by coupling the donor ion to its vibration. We tune our simulator into several parameter regimes and, in particular, investigate the transfer dynamics in the nonperturbative regime often found in biochemical situations.