- Shi, Qiwu;
- Parsonnet, Eric;
- Cheng, Xiaoxing;
- Fedorova, Natalya;
- Peng, Ren-Ci;
- Fernandez, Abel;
- Qualls, Alexander;
- Huang, Xiaoxi;
- Chang, Xue;
- Zhang, Hongrui;
- Pesquera, David;
- Das, Sujit;
- Nikonov, Dmitri;
- Young, Ian;
- Chen, Long-Qing;
- Martin, Lane W;
- Huang, Yen-Lin;
- Íñiguez, Jorge;
- Ramesh, Ramamoorthy
Reducing the switching energy of ferroelectric thin films remains an important goal in the pursuit of ultralow-power ferroelectric memory and logic devices. Here, we elucidate the fundamental role of lattice dynamics in ferroelectric switching by studying both freestanding bismuth ferrite (BiFeO3) membranes and films clamped to a substrate. We observe a distinct evolution of the ferroelectric domain pattern, from striped, 71° ferroelastic domains (spacing of ~100 nm) in clamped BiFeO3 films, to large (10's of micrometers) 180° domains in freestanding films. By removing the constraints imposed by mechanical clamping from the substrate, we can realize a ~40% reduction of the switching voltage and a consequent ~60% improvement in the switching speed. Our findings highlight the importance of a dynamic clamping process occurring during switching, which impacts strain, ferroelectric, and ferrodistortive order parameters and plays a critical role in setting the energetics and dynamics of ferroelectric switching.