- Zhao, Huijuan;
- Zhao, Yingbo;
- Song, Yinxuan;
- Zhou, Ming;
- Lv, Wei;
- Tao, Liu;
- Feng, Yuzhang;
- Song, Biying;
- Ma, Yue;
- Zhang, Junqing;
- Xiao, Jun;
- Wang, Ying;
- Lien, Der-Hsien;
- Amani, Matin;
- Kim, Hyungjin;
- Chen, Xiaoqing;
- Wu, Zhangting;
- Ni, Zhenhua;
- Wang, Peng;
- Shi, Yi;
- Ma, Haibo;
- Zhang, Xiang;
- Xu, Jian-Bin;
- Troisi, Alessandro;
- Javey, Ali;
- Wang, Xinran
Excitons in two-dimensional (2D) materials are tightly bound and exhibit rich physics. So far, the optical excitations in 2D semiconductors are dominated by Wannier-Mott excitons, but molecular systems can host Frenkel excitons (FE) with unique properties. Here, we report a strong optical response in a class of monolayer molecular J-aggregates. The exciton exhibits giant oscillator strength and absorption (over 30% for monolayer) at resonance, as well as photoluminescence quantum yield in the range of 60-100%. We observe evidence of superradiance (including increased oscillator strength, bathochromic shift, reduced linewidth and lifetime) at room-temperature and more progressively towards low temperature. These unique properties only exist in monolayer owing to the large unscreened dipole interactions and suppression of charge-transfer processes. Finally, we demonstrate light-emitting devices with the monolayer J-aggregate. The intrinsic device speed could be beyond 30 GHz, which is promising for next-generation ultrafast on-chip optical communications.