- Lu, Xiaoyan;
- Chen, Zuhuang;
- Cao, Ye;
- Tang, Yunlong;
- Xu, Ruijuan;
- Saremi, Sahar;
- Zhang, Zhan;
- You, Lu;
- Dong, Yongqi;
- Das, Sujit;
- Zhang, Hangbo;
- Zheng, Limei;
- Wu, Huaping;
- Lv, Weiming;
- Xie, Guoqiang;
- Liu, Xingjun;
- Li, Jiangyu;
- Chen, Lang;
- Chen, Long-Qing;
- Cao, Wenwu;
- Martin, Lane W
Ferroelastic switching in ferroelectric/multiferroic oxides plays a crucial role in determining their dielectric, piezoelectric, and magnetoelectric properties. In thin films of these materials, however, substrate clamping is generally thought to limit the electric-field- or mechanical-force-driven responses to the local scale. Here, we report mechanical-force-induced large-area, non-local, collective ferroelastic domain switching in PbTiO3 epitaxial thin films by tuning the misfit-strain to be near a phase boundary wherein c/a and a1/a2 nanodomains coexist. Phenomenological models suggest that the collective, c-a-c-a ferroelastic switching arises from the small potential barrier between the degenerate domain structures, and the large anisotropy of a and c domains, which collectively generates much larger response and large-area domain propagation. Large-area, non-local response under small stimuli, unlike traditional local response to external field, provides an opportunity of unique response to local stimuli, which has potential for use in high-sensitivity pressure sensors and switches.