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Open Access Publications from the University of California

Optimized Designs and Materials for Nanostructure Based Solar Cells

  • Author(s): Shao, Qinghui
  • Advisor(s): Balandin, Alexander A
  • et al.

Nanostructure-based solar cells are attracting significant attention as possible candidates for drastic improvement in photovoltaic (PV) energy conversion efficiency. Although such solar cells are expected to be more expensive there is growing need for the efficient and light-weight solar cells in aero-space and related industries. In this dissertation I present results of the theoretical, computational and experimental investigation of novel designs for quantum dot superlattice (QDS) based PV elements and advanced materials for transparent solar cells. In the first part of the dissertation I describe possible implementation of the intermediate-band (IB) solar cells with QDS. The IB cells were predicted to have PV efficiency exceeding the Shockley-Queisser limit for a single junction cell. The parameters of QDS structure have to be carefully tuned to achieve the desired charge carrier dispersion required for the IB operation. The first-principles models were used to calculate the electrical properties and light absorption in QDS. This approach allowed me to determine the dimensions of QDS for inducing the mini-band which plays the role of the IB. Using the detailed balance theory it was determined that the upper-bound PV efficiency of such IB solar cells can be as high as ~51%. The required QDS dimensions on the basis of InAsN/GaAsSb are technologically challenging but feasible: ~2-6 nm. Using the developed simulation tools I proposed several possible designs of QDS solar cells including one, which combined the benefits of the IB concept and the advanced tandem cell design. The second part of the dissertation presents a study of graphene layers as transparent electrodes for the PV cells. The graphene layers were mechanically exfoliated from bulk graphite and characterized with micro-Raman spectroscopy. It was found that graphene electrodes have good electrical conductivity, which reveals unusual temperature dependence beneficial for the proposed application. The decrease in resistance with temperature was explained by the thermal generation of the electron-hole pairs in the conditions when the carrier mobility is limited by the defect scattering. The final part of the dissertation presents simulation results of electrical current transport in graphene ribbons, which can be used as transparent electrodes or interconnects.

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