College of Engineering

The most efficient and stable combustion occurs in a catalytic reactor when the burning mixture is in contact with the catalyst for a sufficiently long period. When the contract period is too short, insufficient energy is generated adjacent to the catalyst surface to sustain combustion in the main or free stream. This study is focused mainly upon the essential combustion characteristics of propane-air mixtures in flow tube reactors with a heat-recirculating structure. Computational fluid dynamics simulations are performed to gain a greater understanding of the mechanisms of flame stabilization. The essential factors affecting flame stability and combustion characteristics are determined in order to obtain design insights. The results indicate that in order to meet the emission level requirements, for industrial low emission gas turbine engines, staged combustion is required in order to minimise the quantity of the oxides of nitrogen produced. The combustion catalyst has several desirable characteristics: they are capable of minimizing nitrogen oxides emission and improving the pattern factor. Operating the combustion process in a very lean condition, namely high excess air, is one of the simplest ways of achieving lower temperatures and hence lower nitrogen oxides emissions. The use of a catalytic combustor offers the advantage that all of the fuel can be oxidized therein, resulting in ultra-low nitrogen oxides emissions and low carbon monoxide and unburned hydrocarbon levels. In mass transfer controlled catalytic reactions, one cannot distinguish between a more active catalyst and a less active catalyst because the intrinsic catalyst activity is not determinative of the rate of reaction. It is possible to achieve essentially adiabatic combustion in the presence of a catalyst at a reaction rate many times greater than the mass transfer limited rate. The maximum achievable velocity depends on flow conditions and catalyst parameters such as type, monolith cell size, and web thickness.