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Open Access Publications from the University of California

Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents.

  • Author(s): Jung, Dahee;
  • Raffan-Montoya, Fernando;
  • Ramachandran, Roshini;
  • Zhang, Yuanyuan;
  • Islamoglu, Timur;
  • Marin, Gustavo;
  • Qian, Elaine A;
  • Dziedzic, Rafal M;
  • Farha, Omar K;
  • Stoliarov, Stanislav I;
  • Spokoyny, Alexander M
  • et al.

We report the discovery that a perhydroxylated dodecaborate cluster ([B12(OH)12]2-) can act as an inorganic polyol, serving as a molecular cross-linker in the synthesis of polyurethane-based materials. We further demonstrate how the inherent robustness of the utilized boron cluster can effectively enhance the thermal stability of the produced polyurethane materials incorporating [B12(OH)12]2- building blocks compared to analogous polymers made from carbon-based polyols. Ultimately, this approach provides a potential route to tune the chemical and physical properties of soft materials through incorporation of polyhedral boron-rich clusters into the polymer network.

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