Skip to main content
eScholarship
Open Access Publications from the University of California

Characterization of Reactive Organometallic Species via MicroED.

  • Author(s): Jones, Christopher G
  • Asay, Matthew
  • Kim, Lee Joon
  • Kleinsasser, Jack F
  • Saha, Ambarneil
  • Fulton, Tyler J
  • Berkley, Kevin R
  • Cascio, Duilio
  • Malyutin, Andrey G
  • Conley, Matthew P
  • Stoltz, Brian M
  • Lavallo, Vincent
  • Rodríguez, José A
  • Nelson, Hosea M
  • et al.
Abstract

Here we apply microcrystal electron diffraction (MicroED) to the structural determination of transition-metal complexes. We find that the simultaneous use of 300 keV electrons, very low electron doses, and an ultrasensitive camera allows for the collection of data without cryogenic cooling of the stage. This technique reveals the first crystal structures of the classic zirconocene hydride, colloquially known as "Schwartz's reagent", a novel Pd(II) complex not amenable to solution-state NMR or X-ray crystallography, and five other paramagnetic and diamagnetic transition-metal complexes.

Many UC-authored scholarly publications are freely available on this site because of the UC's open access policies. Let us know how this access is important for you.

Main Content
Current View