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Unprecedented superstructure in the type I family of clathrates.
Published Web Locationhttps://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc05167a
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The first arsenic-based clathrate exhibiting superstructural ordering due to optimization of Au-As, As-As, and Ba-Au bonding is reported. Ba8Au16As30 crystallizes in a unique P21/c monoclinic clathrate structure. The synthesis, crystal and electronic structure, and transport properties are discussed.
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