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Investigation of redox switchable titanium and zirconium catalysts for the ring opening polymerization of cyclic esters and epoxides

  • Author(s): Lowe, Miranda Y;
  • Shu, Sisheng;
  • Quan, Stephanie M;
  • Diaconescu, Paula L
  • et al.
Abstract

The synthesis and characterization of (thiolfan*)Zr(OtBu)2 (thiolfan* = 1,1′-di(2,4-di-tert-butyl-6-thiophenoxide)ferrocene) is reported, as well as its activity toward the ring-opening polymerizations of l-lactide and ε-caprolactone.

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