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Investigation of redox switchable titanium and zirconium catalysts for the ring opening polymerization of cyclic esters and epoxides
- Author(s): Lowe, Miranda Y
- Shu, Sisheng
- Quan, Stephanie M
- Diaconescu, Paula L
- et al.
Published Web Locationhttps://doi.org/10.1039/c7qi00227k
The synthesis and characterization of (thiolfan*)Zr(OtBu)2 (thiolfan* = 1,1′-di(2,4-di-tert-butyl-6-thiophenoxide)ferrocene) is reported, as well as its activity toward the ring-opening polymerizations of l-lactide and ε-caprolactone.