Lawrence Berkeley National Laboratory
Highly luminescent phosphine oxide-containing bipolar alkynylgold(iii) complexes for solution-processable organic light-emitting devices with small efficiency roll-offs.
- Author(s): Lee, Chin-Ho
- Tang, Man-Chung
- Cheung, Wai-Lung
- Lai, Shiu-Lun
- Chan, Mei-Yee
- Yam, Vivian Wing-Wah
- et al.
Published Web Locationhttps://doi.org/10.1039/c8sc02265h
We report the synthesis of alkynylgold(iii) complexes with an electron-transporting phosphine oxide moiety in the tridentate ligand and hole-transporting triarylamine moieties as auxiliary ligands to generate a new class of phosphine oxide-containing bipolar gold(iii) complexes for the first time. Such gold(iii) complexes feature high photoluminescence quantum yields of over 70% in 1,3-bis(N-carbazolyl)benzene thin films with relatively short excited-state lifetimes of less than 3.9 μs at a 20 wt% dopant concentration. Highly efficient solution-processable organic light-emitting devices have been prepared with superior current efficiencies of up to 51.6 cd A-1 and external quantum efficiencies of up to 15.3%. Notably, triplet-triplet annihilation has been significantly reduced, as exemplified by a very small efficiency roll-off of ∼1% at a practical brightness of 500 cd m-2.