It is now understood that the accretion of terrestrial planets naturally involves giant collisions, the moon-forming impact being a well-known example. In the aftermath of such collisions, the surface of the surviving planet is very hot and potentially detectable. Here we explore the atmospheric chemistry, photochemistry, and spectral signatures of post-giant-impact terrestrial planets enveloped by thick atmospheres consisting predominantly of CO2 and H2O. The atmospheric chemistry and structure are computed self-consistently for atmospheres in equilibrium with hot surfaces with composition reflecting either the bulk silicate Earth (which includes the crust, mantle, atmosphere, and oceans) or Earth's continental crust. We account for all major molecular and atomic opacity sources including collision-induced absorption. We find that these atmospheres are dominated by H2O and CO2, while the formation of CH4 and NH3 is quenched because of short dynamical timescales. Other important constituents are HF, HCl, NaCl, and SO2. These are apparent in the emerging spectra and can be indicative that an impact has occurred. The use of comprehensive opacities results in spectra that are a factor of two lower brightness temperature in the spectral windows than predicted by previous models. The estimated luminosities show that the hottest post-giant-impact planets will be detectable with near-infrared coronagraphs on the planned 30 m class telescopes. The 1-4 μm will be most favorable for such detections, offering bright features and better contrast between the planet and a potential debris disk. We derive cooling timescales on the order of 105-6 yr on the basis of the modeled effective temperatures. This leads to the possibility of discovering tens of such planets in future surveys. © 2014. The American Astronomical Society. All rights reserved..

Using the Keck Planet Imager and Characterizer, we obtained high-resolution (R ∼ 35,000) K-band spectra of the four planets orbiting HR 8799. We clearly detected H2O and CO in the atmospheres of HR 8799 c, d, and e, and tentatively detected a combination of CO and H2O in b. These are the most challenging directly imaged exoplanets that have been observed at high spectral resolution to date when considering both their angular separations and flux ratios. We developed a forward-modeling framework that allows us to jointly fit the spectra of the planets and the diffracted starlight simultaneously in a likelihood-based approach and obtained posterior probabilities on their effective temperatures, surface gravities, radial velocities, and spins. We measured v sin (i) values of 10.1-2.7+2.8km s-1 for HR 8799 d and 15.0-2.6+2.3 km s-1 for HR 8799 e, and placed an upper limit of <14 km s-1 of HR 8799 c. Under two different assumptions of their obliquities, we found tentative evidence that rotation velocity is anticorrelated with companion mass, which could indicate that magnetic braking with a circumplanetary disk at early times is less efficient at spinning down lower-mass planets.

We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in our ability to model exoplanet atmospheric opacities, clouds, and chemistry, building off a larger 2016 white paper, and endorsed by the NAS Exoplanet Science Strategy report. Now is the ideal time for progress in these areas, but this progress requires better access to, understanding of, and training in the production of spectroscopic data as well as a better insight into chemical reaction kinetics both thermal and radiation-induced at a broad range of temperatures. Given that most published efforts have emphasized relatively Earth-like conditions, we can expect significant and enlightening discoveries as emphasis moves to the exotic atmospheres of exoplanets.