The authors regret that a technical mistake has been discovered, which impacts the current density and power density reported in this article. Briefly, the mistake was caused by catalyst solution leaking out of the intended 1 cm2 catalyzed area and depositing catalyst over the whole cell. As a result, the calculated current and power densities (total divided by the catalyzed area) were higher than reality because the measured current and power were dividing by the intended 1 cm2 instead of the actual area including the leakage, which was approximately 5 cm2. This issue is presented, analysed, and discussed in further detail in the supporting information of Reference 1. The authors would like to apologise for any inconvenience caused.

Internal reforming of ethanol fuel was investigated on high-performance metal-supported solid oxide fuel cells (MS-SOFCs) with infiltrated catalysts. The hydrogen concentration and internal reforming effects were evaluated systematically with different fuels including: hydrogen, simulated reformate, anhydrous ethanol, ethanol water blend, and hydrogen-nitrogen mixtures. A simple infiltration of Ni reforming catalyst into 40 vol% Ni-Sm0.20Ce0.80O2-δ (Ni-SDCN40) and fuel-side metal support leads to complete internal reforming, as confirmed by comparison to simulated reformate. The performance difference between hydrogen and fully-reformed ethanol is attributed entirely to decrease in hydrogen concentration. High peak power density was achieved for a range of conditions, for example 1.0 W cm−2 at 650 °C in ethanol-water blend, and 1.4 W cm−2 at 700 °C in anhydrous ethanol fuel. Initial durability tests with ethanol-water blend show promising stability for 100 h at 700 °C and 0.7 V. Carbon is not deposited in the Ni-SDCN40 anode during operation.

Performance of symmetric-architecture metal-supported solid oxide fuel cells was improved significantly by optimizing the catalyst infiltration process and metal support structure. Optimization of component structure and processing parameters was performed during tape-casting and fabrication of button cells. Mass transport of oxygen in the metal support was identified as a major limitation. To overcome this limitation, pore former loading and thickness of the metal support (130–250 μm) were optimized. The catalyst infiltration process was also improved by studying the impact of firing temperature (400 °C–900 °C) and infiltration cycle numbers (1–15). The maximum power density of the optimized cell was 0.9 W cm−2 at 700 °C using hydrogen as a fuel, a three-fold increase over the baseline cell performance. The degradation rate of optimized cells at 550 °C, 600 °C, and 700 °C was 2%, 4.5%, and 5.5% per 100 h, respectively. The phenomena of mass transport, catalyst coarsening, and chromium poisoning on the catalyst were analyzed by electrochemical impedance spectroscopy and scanning electron microscopy.