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Scholarly Works (1 results)

Article
Peer Reviewed

Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al 13 chloride

Gu, Bin;
Sun, Chenglin;
Fettinger, James C;
Casey, William H;
Dikhtiarenko, Alla;
Gascon, Jorge;
Koichumanova, Kamila;
Babu Sai Sankar Gupta, Karthick;
Jan Heeres, Hero;
He, Songbo

UC Davis Previously Published Works (2018)

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

Cover page: Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al 13 chloride