This book presents a systematic attempt to generalize several fundamental physical laws related to subsurface fluid flow that are important for a number of contemporary applications in the areas of hydrogeology, reservoir engineering and ...

We have developed a new coal-permeability model for uniaxial strain and constant confining-stress conditions. The model is unique in that it explicitly considers fracture–matrix interaction during coal-deformation processes and is based on a newly proposed internal swelling stress concept. This concept is used to account for the impact of matrix swelling (or shrinkage) on fracture-aperture changes resulting from partial separation of matrix blocks by fractures that do not completely cut through the whole matrix. The proposed permeability model is evaluated using data from three Valencia Canyon coalbed wells in the San Juan Basin, where increased permeability has been observed during CH4 gas production, as well as using published data from laboratory tests. Model results are generally in good agreement with observed permeability changes. The importance of fracture–matrix interaction in determining coal permeability, demonstrated in this study using relatively simple stress conditions, underscores the need for a dual-continuum (fracture and matrix) mechanical approach to rigorously capture coal-deformation processes under complex stress conditions, as well as the coupled flow and transport processes in coal seams.

One of the most important design variables for a geological nuclear waste repository is the temperature limit up to which the engineered barrier system (EBS) and the natural geologic environment can be exposed. Up to now, almost all design concepts that involve bentonite-backfilled emplacement tunnels have chosen a maximum allowable temperature of about 100. °C. Such a choice is largely based on the consideration that in clay-based materials illitization and the associated mechanical changes in the bentonite (and perhaps the clay host rock) could affect the barrier attributes of the EBS. However, existing experimental and modeling studies on the occurrence of illitization and related performance impacts are not conclusive, in part because the relevant couplings between the thermal, hydrological, chemical, and mechanical (THMC) processes have not been fully represented in the models. This paper presents a fully coupled THMC simulation of a nuclear waste repository in a clay formation with a bentonite-backfilled EBS for 1000. years. Two scenarios were simulated for comparison: a case in which the temperature in the bentonite near the waste canister can reach about 200. °C and a case in which the temperature in the bentonite near the waste canister peaks at about 100. °C.The model simulations demonstrate some degree of illitization in both the bentonite buffer and the surrounding clay formation. Other chemical alterations include the dissolution of K-feldspar and calcite, and precipitation of quartz, chlorite, and kaolinite. In general, illitization in the bentonite and the clay formation is enhanced at higher temperature. However, the quantity of illitization is affected by many chemical factors and therefore varies a great deal. The most important chemical factors are the concentration of K in the pore water as well as the abundance and dissolution rate of K-feldspar less important ones are the concentration of sodium and the quartz precipitation rate. In our modeling scenarios, the calculated decrease in smectite volume fraction in bentonite ranges from 1 to 8% of the initial volume fraction of smectite in the 100. °C scenario and 1-27% in the 200. °C scenario. Chemical changes in the 200. °C scenario could also lead to a reduction in swelling stress up to 15-18% whereas those in the 100. °C scenario result in about 14-15% reduction in swelling stress for the base case scenario. Model results also show that the 200. °C scenario results in a much higher total stress than the 100. °C scenario, mostly due to thermal pressurization. While cautions should be taken regarding the model results due to some limitations in the models, the modeling work is illustrative in light of the relative importance of different processes occurring in EBS bentonite and clay formation at higher than 100. °C conditions, and could be of greater use when site specific data are available.