In-situ X-ray diffraction (XRD) measurements using high energy synchrotron radiation were performed to monitor in real time the formation of delta ferrite in a martensitic 9 wt pct chromium steel under simulated weld thermal cycles. Volume fractions of martensite, austenite, and delta ferrite were measured as a function of temperature at a 10 K/s heating rate to 1573 K (1300 °C) and subsequent cooling. At the peak temperature, the delta ferrite concentration rose to 19 pct, of which 17 pct transformed back to austenite on subsequent cooling.