- Barrozo, Petrucio;
- Småbråten, Didrik René;
- Tang, Yun‐Long;
- Prasad, Bhagwati;
- Saremi, Sahar;
- Ozgur, Rustem;
- Thakare, Vishal;
- Steinhardt, Rachel A;
- Holtz, Megan E;
- Stoica, Vladimir Alexandru;
- Martin, Lane W;
- Schlom, Darrel G;
- Selbach, Sverre Magnus;
- Ramesh, Ramamoorthy
Results of switching behavior of the improper ferroelectric LuFeO3 are presented. Using a model set of films prepared under controlled chemical and growth-rate conditions, it is shown that defects can reduce the quasi-static switching voltage by up to 40% in qualitative agreement with first-principles calculations. Switching studies show that the coercive field has a stronger frequency dispersion for the improper ferroelectrics compared to a proper ferroelectric such as PbTiO3 . It is concluded that the primary structural order parameter controls the switching dynamics of such improper ferroelectrics.