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Probing Delayed C–I Bond Fission in the UV Photochemistry of 2-Iodothiophene with Core-to-Valence Transient Absorption Spectroscopy
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https://doi.org/10.1364/up.2020.th3a.5Abstract
The UV photodissociation dynamics of 2-iodothiophene are monitored by an XUV probe pulse that promotes iodine 4d core-to-valence transitions. Absorption changes from molecular iodine species conclusively show that dissociation requires up to ~1 picosecond.
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