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Gas Storage and Separations in Metal-Organic Frameworks with Open Metal Sites

  • Author(s): Bloch, Eric Douglas
  • Advisor(s): Long, Jeffrey R.
  • et al.
Abstract

The work presented in this dissertation describes the synthesis and characterization of metal-organic frameworks for gas storage and separation applications. A specific class of materials investigated is metal-organic frameworks containing coordinatively-unsaturated metal cation sites, as these sites perform the bulk of the work for the separations discussed. A wide variety of techniques and spectroscopic methods are covered, including gas adsorption, structural analysis, infrared and Mössbauer spectroscopies, and breakthrough experiments.

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