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Fluorination‐Enhanced Surface Stability of Cation‐Disordered Rocksalt Cathodes for Li‐Ion Batteries


Cation-disordered rocksalt (DRX) materials have emerged as a class of novel high-capacity cathodes for Li-ion batteries. However, the commercialization of DRX cathodes will require reducing their capacity decay, which has been associated with oxygen loss during cycling. Recent studies show that fluorination of DRX cathodes can effectively reduce oxygen loss and improve cycling stability; however, the underlying atomic-scale mechanisms remain elusive. Herein, using a combination of electrochemical measurements, scanning transmission electron microscopy, and electron energy loss spectroscopy, the correlation between the electrochemical properties and structural evolution in Mn-redox-based DRX cathodes, Li1.2Ti0.4–xMn0.4+xO2.0-xFx (x = 0 and 0.2) is examined. It is found that fluorination strongly suppresses structural amorphization and void formation initiated from the particle surface, therefore greatly enhancing the cyclability of the cathode. A novel rocksalt-to-spinel-like structural transformation in the DRX bulk is further revealed, which surprisingly contributes to a gradual capacity increase during cycling. The results provide important insight for the design of novel DRX cathodes with high capacity and long cycle life.

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