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Open Access Publications from the University of California

Nitrogen-Rich Polyacrylonitrile-Based Graphitic Carbons for Hydrogen Peroxide Sensing.

  • Author(s): Pollack, Brandon
  • Holmberg, Sunshine
  • George, Derosh
  • Tran, Ich
  • Madou, Marc
  • Ghazinejad, Maziar
  • et al.

Published Web Location Commons 'BY' version 4.0 license

Catalytic substrate, which is devoid of expensive noble metals and enzymes for hydrogen peroxide (H₂O₂), reduction reactions can be obtained via nitrogen doping of graphite. Here, we report a facile fabrication method for obtaining such nitrogen doped graphitized carbon using polyacrylonitrile (PAN) mats and its use in H₂O₂ sensing. A high degree of graphitization was obtained with a mechanical treatment of the PAN fibers embedded with carbon nanotubes (CNT) prior to the pyrolysis step. The electrochemical testing showed a limit of detection (LOD) 0.609 µM and sensitivity of 2.54 µA cm-2 mM-1. The promising sensing performance of the developed carbon electrodes can be attributed to the presence of high content of pyridinic and graphitic nitrogens in the pyrolytic carbons, as confirmed by X-ray photoelectron spectroscopy. The reported results suggest that, despite their simple fabrication, the hydrogen peroxide sensors developed from pyrolytic carbon nanofibers are comparable with their sophisticated nitrogen-doped graphene counterparts.

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