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Optical response of deep defects as revealed by transient photocapacitance and photocurrent spectroscopy in CdTe/CdS solar cells
- Boucher, JW;
- Miller, DW;
- Warren, CW;
- Cohen, JD;
- McCandless, BE;
- Heath, JT;
- Lonergan, MC;
- Boettcher, SW
Published Web Location
https://doi.org/10.1016/j.solmat.2014.02.024Abstract
Transient photocapacitance (TPC) and photocurrent (TPI) spectroscopy were used to characterize defects in CdTe/CdS solar cells. A broad defect band is observed at an optical energy of 1.28eV above the valence band, and such a defect is not indicated by admittance spectroscopy and drive-level capacitance profiling. Temperature-dependent TPC measurements of the defect band follow a thermal quenching model in which the defect׳s energy, 0.22eV below the conduction band, is consistent with the optical response. We provide a theoretical basis for the use of a thermal quenching model in TPC.
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