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Zn2SbN3: Growth and characterization of a metastable photoactive semiconductor
- Author(s): Arca, E;
- Perkins, JD;
- Lany, S;
- Mis, A;
- Chen, BR;
- Dippo, P;
- Partridge, JL;
- Sun, W;
- Holder, A;
- Tamboli, AC;
- Toney, MF;
- Schelhas, LT;
- Ceder, G;
- Tumas, W;
- Teeter, G;
- Zakutayev, A
- et al.
Published Web Location
https://doi.org/10.1039/c9mh00369jAbstract
Ternary nitride semiconductors with wurtzite-derived crystal structures are an emerging class of materials for optoelectronic applications compatible with GaN and related III-V compounds. In particular, II-IV-V2 materials such as ZnSnN2 and ZnGeN2 have been very actively studied for applications in photovoltaics and light emitting devices. However, many other possible wurtzite-derived ternary nitrides have not been reported, and hence their optical and electrical properties remain unknown. Here, we report on Zn2SbN3-the first Sb-based nitride and a photoactive semiconductor. Surprisingly, Zn2SbN3 contains Sb in the highest (5+) oxidation state, and in the unusual tetrahedral coordination. This new Zn2SbN3 material has a solar-matched 1.6-1.7 eV band gap and shows near-band-edge room-temperature photoluminescence, demonstrating its promise as an optoelectronic semiconductor. Finally, Zn2SbN3 can be synthesized at low temperature under a wide range of processing conditions, despite being metastable according to theoretical calculations. All these results, as well as the band position measurements, indicate that Zn2SbN3 is a promising emerging semiconductor for applications as an absorber in photovoltaic-and photoelectrochemical solar cells.
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