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Ultraconfined Plasmonic Hotspots Inside Graphene Nanobubbles

  • Author(s): Fei, Z
  • Foley, JJ
  • Gannett, W
  • Liu, MK
  • Dai, S
  • Ni, GX
  • Zettl, A
  • Fogler, MM
  • Wiederrecht, GP
  • Gray, SK
  • Basov, DN
  • et al.
Abstract

© 2016 American Chemical Society. We report on a nanoinfrared (IR) imaging study of ultraconfined plasmonic hotspots inside graphene nanobubbles formed in graphene/hexagonal boron nitride (hBN) heterostructures. The volume of these plasmonic hotspots is more than one-million-times smaller than what could be achieved by free-space IR photons, and their real-space distributions are controlled by the sizes and shapes of the nanobubbles. Theoretical analysis indicates that the observed plasmonic hotspots are formed due to a significant increase of the local plasmon wavelength in the nanobubble regions. Such an increase is attributed to the high sensitivity of graphene plasmons to its dielectric environment. Our work presents a novel scheme for plasmonic hotspot formation and sheds light on future applications of graphene nanobubbles for plasmon-enhanced IR spectroscopy.

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