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Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane.
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https://doi.org/10.1039/c6sc02668kAbstract
LCuOTf complexes [L = cyclic (alkyl)(amino)carbenes (CAACs) or N-heterocyclic carbenes (NHCs)] selectively promote the dehydrogenative borylation of C(sp)-H bonds at room temperature. It is shown that σ,π-bis(copper) acetylide and copper hydride complexes are the key catalytic species.
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