- Sutter, D;
- Fatuzzo, CG;
- Moser, S;
- Kim, M;
- Fittipaldi, R;
- Vecchione, A;
- Granata, V;
- Sassa, Y;
- Cossalter, F;
- Gatti, G;
- Grioni, M;
- Rønnow, HM;
- Plumb, NC;
- Matt, CE;
- Shi, M;
- Hoesch, M;
- Kim, TK;
- Chang, T-R;
- Jeng, H-T;
- Jozwiak, C;
- Bostwick, A;
- Rotenberg, E;
- Georges, A;
- Neupert, T;
- Chang, J
A paradigmatic case of multi-band Mott physics including spin-orbit and Hund's coupling is realized in Ca2RuO4. Progress in understanding the nature of this Mott insulating phase has been impeded by the lack of knowledge about the low-energy electronic structure. Here we provide-using angle-resolved photoemission electron spectroscopy-the band structure of the paramagnetic insulating phase of Ca2RuO4 and show how it features several distinct energy scales. Comparison to a simple analysis of atomic multiplets provides a quantitative estimate of the Hund's coupling J=0.4 eV. Furthermore, the experimental spectra are in good agreement with electronic structure calculations performed with Dynamical Mean-Field Theory. The crystal field stabilization of the dxy orbital due to c-axis contraction is shown to be essential to explain the insulating phase. These results underscore the importance of multi-band physics, Coulomb interaction and Hund's coupling that together generate the Mott insulating state of Ca2RuO4.