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Open Access Publications from the University of California

Inorganic-organic hybrids derived from oxovanadium sulfate motifs: Synthesis and characterization of [VIVO(μ3-SO4)(2,2’-bpy)]∞

  • Author(s): Khan, MI
  • Cevik, S
  • Doedens, RJ
  • et al.

Published Web Location Commons Attribution 4.0 International Public License

The hydrothermal reaction of V2O5, V2O3, 2,2’-bpy and Na2SO4in dilute sulfuric acid yields a novel hybrid, [VIVO(μ3-SO4)(2,2’-bpy)]∞, which demonstrates the potential of constructing a new class of robust composite solids composed of a {V/O/SO4}-based framework decorated with organic functionalities by combining appropriate vanadyl sulfate motifs with a variety of organic ligands. © 2001 Royal Society of Chemistry.

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